Deep Operator Networks (DeepONets) provide a branch-trunk neural architecture for approximating nonlinear operators acting between function spaces. In the classical operator approximation framework, the input is a function $u\in C(K_1)$ defined on a compact set $K_1$ (typically a compact subset of a Banach space), and the operator maps $u$ to an output function $G(u)\in C(K_2)$ defined on a compact Euclidean domain $K_2\subset\mathbb{R}^d$. In this paper, we develop a topological extension in which the operator input lies in an arbitrary Hausdorff locally convex space $X$. We construct topological feedforward neural networks on $X$ using continuous linear functionals from the dual space $X^*$ and introduce topological DeepONets whose branch component acts on $X$ through such linear measurements, while the trunk component acts on the Euclidean output domain. Our main theorem shows that continuous operators $G:V\to C(K;\mathbb{R}^m)$, where $V\subset X$ and $K\subset\mathbb{R}^d$ are compact, can be uniformly approximated by such topological DeepONets. This extends the classical Chen-Chen operator approximation theorem from spaces of continuous functions to locally convex spaces and yields a branch-trunk approximation theorem beyond the Banach-space setting.