We consider the problem of clock synchronization in a wireless setting where processors must power-down their radios in order to save energy. Energy efficiency is a central goal in wireless networks, especially if energy resources are severely limited. In the current setting, the problem is to synchronize clocks of $m$ processors that wake up in arbitrary time points, such that the maximum difference between wake up times is bounded by a positive integer $n$, where time intervals are appropriately discretized. Currently, the best-known results for synchronization for single-hop networks of $m$ processors is a randomized algorithm due to \cite{BKO09} of O(\sqrt {n /m} \cdot poly-log(n)) awake times per processor and a lower bound of Omega(\sqrt{n/m}) of the number of awake times needed per processor \cite{BKO09}. The main open question left in their work is to close the poly-log gap between the upper and the lower bound and to de-randomize their probabilistic construction and eliminate error probability. This is exactly what we do in this paper. That is, we show a {deterministic} algorithm with radio use of Theta(\sqrt {n /m}) that never fails. We stress that our upper bound exactly matches the lower bound proven in \cite{BKO09}, up to a small multiplicative constant. Therefore, our algorithm is {optimal} in terms of energy efficiency and completely resolves a long sequence of works in this area. In order to achieve these results we devise a novel {adaptive} technique that determines the times when devices power their radios on and off. In addition, we prove several lower bounds on the energy efficiency of algorithms for {multi-hop networks}. Specifically, we show that any algorithm for multi-hop networks must have radio use of Omega(\sqrt n) per processor.