We consider the coflow scheduling problem in the non-clairvoyant setting, assuming that flow sizes are realized on-line according to given probability distributions. The goal is to minimize the weighted average completion time of coflows in expectation. We first obtain inequalities for this problem that are valid for all non-anticipative order-based rate-allocation policies and define a polyhedral relaxation of the performance space of such scheduling policies. This relaxation is used to analyze the performance of a simple priority policy in which the priority order is computed by Sincronia from expected flow sizes instead of their unknown actual values. We establish a bound on the approximation ratio of this priority policy with respect to the optimal priority policy for arbitrary probability distributions of flow sizes (with finite first and second moments). Tighter upper bounds are obtained for some specific distributions. Extensive numerical results suggest that performance of the proposed policy is much better than the upper bound.