The convergence of blockchain and the Internet of Things (IoT) enables secure, decentralised, and verifiable data exchange across distributed smart environments. However, traditional blockchain frameworks suffer from inherent scalability constraints, limited throughput, and high latency, which conflict with the stringent real-time requirements of IoT applications such as industrial automation, intelligent healthcare, and smart transportation. These systems demand ultra-low latency, high transaction throughput, lightweight computation, and efficient resource utilisation. This review provides a comprehensive, structured analysis of state-of-the-art scalability solutions specifically adapted to blockchain-enabled IoT. The discussion encompasses Layer 1 enhancements, Layer 2 off-chain processing, sharding-based parallelisation, integration of edge and fog computing, and hybrid consensus mechanisms. For each approach, the review highlights operational principles, performance benefits, trade-offs in decentralisation and security, and suitability for latency-sensitive deployments. Furthermore, real-time quality-of-service considerations are examined to understand how scalability strategies impact system responsiveness, energy efficiency, and data integrity. Key open challenges, including the scalability-security trade-off, privacy preservation, interoperability, and sustainable resource management, have been identified as persistent barriers to large-scale adoption. Finally, the review outlines future research directions, emphasising adaptive and AI-driven consensus algorithms, quantum-safe cryptographic models, the convergence of blockchain with 5G/6G networks, and edge intelligence. By consolidating diverse technical insights and emerging trends, this work serves as a timely reference for developing scalable, secure, and sustainable blockchain architectures for real-time IoT applications.