Energy-aware architectures provide applications with a mix of low (LITTLE) and high (big) frequency cores. Choosing the best hardware configuration for a program running on such an architecture is difficult, because program parts benefit differently from the same hardware configuration. State-of-the-art techniques to solve this problem adapt the program's execution to dynamic characteristics of the runtime environment, such as energy consumption and throughput. We claim that these purely dynamic techniques can be improved if they are aware of the program's syntactic structure. To support this claim, we show how to use the compiler to partition source code into program phases: regions whose syntactic characteristics lead to similar runtime behavior. We use reinforcement learning to map pairs formed by a program phase and a hardware state to the configuration that best fit this setup. To demonstrate the effectiveness of our ideas, we have implemented the Astro system. Astro uses Q-learning to associate syntactic features of programs with hardware configurations. As a proof of concept, we provide evidence that Astro outperforms GTS, the ARM-based Linux scheduler tailored for heterogeneous architectures, on the parallel benchmarks from Rodinia and Parsec.