Decentralized federated learning (D-FL) allows clients to aggregate learning models locally, offering flexibility and scalability. Existing D-FL methods use gossip protocols, which are inefficient when not all nodes in the network are D-FL clients. This paper puts forth a new D-FL strategy, termed Route-and-Aggregate (R&A) D-FL, where participating clients exchange models with their peers through established routes (as opposed to flooding) and adaptively normalize their aggregation coefficients to compensate for communication errors. The impact of routing and imperfect links on the convergence of R&A D-FL is analyzed, revealing that convergence is minimized when routes with the minimum end-to-end packet error rates are employed to deliver models. Our analysis is experimentally validated through three image classification tasks and two next-word prediction tasks, utilizing widely recognized datasets and models. R&A D-FL outperforms the flooding-based D-FL method in terms of training accuracy by 35% in our tested 10-client network, and shows strong synergy between D-FL and networking. In another test with 10 D-FL clients, the training accuracy of R&A D-FL with communication errors approaches that of the ideal C-FL without communication errors, as the number of routing nodes (i.e., nodes that do not participate in the training of D-FL) rises to 28.