The exponential growth of large language models has outpaced the capabilities of traditional CPU and GPU architectures due to the slowdown of Moore's Law. Dataflow AI accelerators present a promising alternative; however, there remains a lack of in-depth performance analysis and standardized benchmarking methodologies for LLM training. We introduce DABench-LLM, the first benchmarking framework designed for evaluating LLM workloads on dataflow-based accelerators. By combining intra-chip performance profiling and inter-chip scalability analysis, DABench-LLM enables comprehensive evaluation across key metrics such as resource allocation, load balance, and resource efficiency. The framework helps researchers rapidly gain insights into underlying hardware and system behaviors, and provides guidance for performance optimizations. We validate DABench-LLM on three commodity dataflow accelerators, Cerebras WSE-2, SambaNova RDU, and Graphcore IPU. Our framework reveals performance bottlenecks and provides specific optimization strategies, demonstrating its generality and effectiveness across a diverse range of dataflow-based AI hardware platforms.