The creation of high-quality ontologies is crucial for data integration and knowledge-based reasoning, specifically in the context of the rising data economy. However, automatic ontology matchers are often bound to the heuristics they are based on, leaving many matches unidentified. Interactive ontology matching systems involving human experts have been introduced, but they do not solve the fundamental issue of flexibly finding additional matches outside the scope of the implemented heuristics, even though this is highly demanded in industrial settings. Active machine learning methods appear to be a promising path towards a flexible interactive ontology matcher. However, off-the-shelf active learning mechanisms suffer from low query efficiency due to extreme class imbalance, resulting in a last-mile problem where high human effort is required to identify the remaining matches. To address the last-mile problem, this work introduces DualLoop, an active learning method tailored to ontology matching. DualLoop offers three main contributions: (1) an ensemble of tunable heuristic matchers, (2) a short-term learner with a novel query strategy adapted to highly imbalanced data, and (3) long-term learners to explore potential matches by creating and tuning new heuristics. We evaluated DualLoop on three datasets of varying sizes and domains. Compared to existing active learning methods, we consistently achieved better F1 scores and recall, reducing the expected query cost spent on finding 90% of all matches by over 50%. Compared to traditional interactive ontology matchers, we are able to find additional, last-mile matches. Finally, we detail the successful deployment of our approach within an actual product and report its operational performance results within the Architecture, Engineering, and Construction (AEC) industry sector, showcasing its practical value and efficiency.