In a XOR-based alternating block cipher the plaintext is masked by a sequence of layers each performing distinct actions: a highly nonlinear permutation, a linear transformation, and the bitwise key addition. When assessing resistance against classical differential attacks (where differences are computed with respect to XOR), the cryptanalysts must only take into account differential probabilities introduced by the nonlinear layer, this being the only one whose differential transitions are not deterministic. The temptation of computing differentials with respect to another difference operation runs into the difficulty of understanding how differentials propagate through the XOR-affine levels of the cipher. In this paper we introduce a special family of braces that enable the derivation of a set of differences whose interaction with every layer of an XOR-based alternating block cipher can be understood. We show that such braces can be described also in terms of alternating binary algebras of nilpotency class two. Additionally, we present a method to compute the automorphism group of these structures through an equivalence between bilinear maps. By doing so, we characterise the XOR-linear permutations for which the differential transitions with respect to the new difference are deterministic, facilitating an alternative differential attack.