The goal of this paper is to rigorously interrogate conventional wisdom about centralization in block-building (due to, e.g., MEV and private order flow) and the outsourcing of block-building by validators to specialists (i.e., proposer-builder separation): 1. Does heterogeneity in skills and knowledge across block producers inevitably lead to centralization? 2. Does proposer-builder separation eliminate heterogeneity and preserve decentralization among proposers? This paper develops mathematical models and results that offer answers to these questions: 1. In a game-theoretic model with endogenous staking, heterogeneous block producer rewards, and staking costs, we quantify the extent to which heterogeneous rewards lead to concentration in the equilibrium staking distribution. 2. In a stochastic model in which heterogeneous block producers repeatedly reinvest rewards into staking, we quantify, as a function of the block producer heterogeneity, the rate at which stake concentrates on the most sophisticated block producers. 3. In a model with heterogeneous proposers and specialized builders, we quantify, as a function of the competitiveness of the builder ecosystem, the extent to which proposer-builder separation reduces the heterogeneity in rewards across different proposers. Our models and results take advantage of connections to contest design, Pólya urn processes, and auction theory.