In Industry 4.0 systems, a considerable number of resource-constrained Industrial Internet of Things (IIoT) devices engage in frequent data interactions due to the necessity for model training, which gives rise to concerns pertaining to security and privacy. In order to address these challenges, this paper considers a digital twin (DT) and blockchain-assisted federated learning (FL) scheme. To facilitate the FL process, we initially employ fog devices with abundant computational capabilities to generate DT for resource-constrained edge devices, thereby aiding them in local training. Subsequently, we formulate an FL delay minimization problem for FL, which considers both of model transmission time and synchronization time, also incorporates cooperative jamming to ensure secure synchronization of DT. To address this non-convex optimization problem, we propose a decomposition algorithm. In particular, we introduce upper limits on the local device training delay and the effects of aggregation jamming as auxiliary variables, thereby transforming the problem into a convex optimization problem that can be decomposed for independent solution. Finally, a blockchain verification mechanism is employed to guarantee the integrity of the model uploading throughout the FL process and the identities of the participants. The final global model is obtained from the verified local and global models within the blockchain through the application of deep learning techniques. The efficacy of our proposed cooperative interference-based FL process has been verified through numerical analysis, which demonstrates that the integrated DT blockchain-assisted FL scheme significantly outperforms the benchmark schemes in terms of execution time, block optimization, and accuracy.