As a key technology in 6G research, federated learning (FL) enables collaborative learning among multiple clients while ensuring individual data privacy. However, malicious attackers among the participating clients can intentionally tamper with the training data or the trained model, compromising the accuracy and trustworthiness of the system. To address this issue, in this paper, we propose a hierarchical audit-based FL (HiAudit-FL) framework, with the aim to enhance the reliability and security of the learning process. The hierarchical audit process includes two stages, namely model-audit and parameter-audit. In the model-audit stage, a low-overhead audit method is employed to identify suspicious clients. Subsequently, in the parameter-audit stage, a resource-consuming method is used to detect all malicious clients with higher accuracy among the suspicious ones. Specifically, we execute the model audit method among partial clients for multiple rounds, which is modeled as a partial observation Markov decision process (POMDP) with the aim to enhance the robustness and accountability of the decision-making in complex and uncertain environments. Meanwhile, we formulate the problem of identifying malicious attackers through a multi-round audit as an active sequential hypothesis testing problem and leverage a diffusion model-based AI-Enabled audit selection strategy (ASS) to decide which clients should be audited in each round. To accomplish efficient and effective audit selection, we design a DRL-ASS algorithm by incorporating the ASS in a deep reinforcement learning (DRL) framework. Our simulation results demonstrate that HiAudit-FL can effectively identify and handle potential malicious users accurately, with small system overhead.