Post-Training Quantization (PTQ) reduces the memory footprint and computational overhead of deep neural networks by converting full-precision (FP) values into quantized and compressed data types. While PTQ is more cost-efficient than Quantization-Aware Training (QAT), it is highly susceptible to accuracy degradation under a low-bit quantization (LQ) regime (e.g., 2-bit). Affine transformation is a classical technique used to reduce the discrepancy between the information processed by a quantized model and that processed by its full-precision counterpart; however, we find that using plain affine transformation, which applies a uniform affine parameter set for all outputs, worsens the results in low-bit PTQ. To address this, we propose Cluster-based Affine Transformation (CAT), an error-reduction framework that employs cluster-specific parameters to align LQ outputs with FP counterparts. CAT refines LQ outputs with only a negligible number of additional parameters, without requiring fine-tuning of the model or quantization parameters. We further introduce a novel PTQ framework integrated with CAT. Experiments on ImageNet-1K show that this framework consistently outperforms prior PTQ methods across diverse architectures and LQ settings, achieving up to 53.18% Top-1 accuracy on W2A2 ResNet-18. Moreover, CAT enhances existing PTQ baselines by more than 3% when used as a plug-in. We plan to release our implementation alongside the publication of this paper.