Document visual question answering requires models not only to answer questions correctly, but also to precisely localize answers within complex document layouts. While large vision-language models (VLMs) achieve strong spatial grounding, their inference cost and latency limit real-world deployment. Compact VLMs are more efficient, but they often suffer substantial localization degradation under standard fine-tuning or distillation. To address this gap, we propose DocVAL, a validated chain-of-thought (CoT) distillation framework that transfers explicit spatial reasoning from large teacher models to compact, deployable student VLMs. DocVAL combines (1) teacher-generated spatial CoT supervision, (2) a rule-based dual-mode validator that filters low-quality training signals and provides fine-grained, pixel-level corrective feedback, and (3) a validation-driven two-stage training procedure with iterative refinement. Text detection is used only as training-time scaffolding for supervision and validation, enabling the final student to operate as a pure VLM without OCR or detection at inference. Across multiple document understanding benchmarks, DocVAL yields consistent improvements of up to 6-7 ANLS points over comparable compact VLMs. We further introduce mean Average Precision (mAP) as a localization metric for document question answering and report strong spatial grounding performance under this new evaluation. We release 95K validator-verified CoT traces and show that high-quality, validated supervision is more effective than scaling unfiltered data, enabling efficient and trustworthy document grounding. Code/Data: https://github.com/ahmad-shirazi/DocVAL