Research on unsupervised domain adaptation (UDA) for semantic segmentation of remote sensing images has been extensively conducted. However, research on how to achieve domain adaptation in practical scenarios where source domain data is inaccessible namely, source-free domain adaptation (SFDA) remains limited. Self-training has been widely used in SFDA, which requires obtaining as many high-quality pseudo-labels as possible to train models on target domain data. Most existing methods optimize the entire pseudo-label set to obtain more supervisory information. However, as pseudo-label sets often contain substantial noise, simultaneously optimizing all labels is challenging. This limitation undermines the effectiveness of optimization approaches and thus restricts the performance of self-training. To address this, we propose a novel pseudo-label optimization framework called Diffusion-Guided Label Enrichment (DGLE), which starts from a few easily obtained high-quality pseudo-labels and propagates them to a complete set of pseudo-labels while ensuring the quality of newly generated labels. Firstly, a pseudo-label fusion method based on confidence filtering and super-resolution enhancement is proposed, which utilizes cross-validation of details and contextual information to obtain a small number of high-quality pseudo-labels as initial seeds. Then, we leverage the diffusion model to propagate incomplete seed pseudo-labels with irregular distributions due to its strong denoising capability for randomly distributed noise and powerful modeling capacity for complex distributions, thereby generating complete and high-quality pseudo-labels. This method effectively avoids the difficulty of directly optimizing the complete set of pseudo-labels, significantly improves the quality of pseudo-labels, and thus enhances the model's performance in the target domain.