This work investigates the feasibility of a post-processing-based approach for phase separation in defocusing particle tracking velocimetry for dispersed two-phase flows. The method enables the simultaneous 3D localization determination of both tracer particles and particles of the dispersed phase, using a single-camera setup. The distinction between phases is based on pattern differences in defocused particle images, which arise from distinct light scattering behaviors of tracer particles and bubbles or droplets. Convolutional neural networks, including Faster R-CNN and YOLOv4 variants, are trained to detect and classify particle images based on these pattern features. To generate large, labeled training datasets, a generative adversarial network based framework is introduced, allowing the generation of auto-labeled data that more closely reflects experiment-specific visual appearance. Evaluation across six datasets, comprising synthetic two-phase and real single- and two-phase flows, demonstrates high detection precision and classification accuracy (95-100%), even under domain shifts. The results confirm the viability of using CNNs for robust phase separation in disperse two-phase DPTV, particularly in scenarios where traditional wavelength-, size-, or ensemble correlation-based methods are impractical.