Walking assistance in extreme or complex environments remains a significant challenge for people with blindness or low vision (BLV), largely due to the lack of a holistic scene understanding. Motivated by the real-world needs of the BLV community, we build mmWalk, a simulated multi-modal dataset that integrates multi-view sensor and accessibility-oriented features for outdoor safe navigation. Our dataset comprises 120 manually controlled, scenario-categorized walking trajectories with 62k synchronized frames. It contains over 559k panoramic images across RGB, depth, and semantic modalities. Furthermore, to emphasize real-world relevance, each trajectory involves outdoor corner cases and accessibility-specific landmarks for BLV users. Additionally, we generate mmWalkVQA, a VQA benchmark with over 69k visual question-answer triplets across 9 categories tailored for safe and informed walking assistance. We evaluate state-of-the-art Vision-Language Models (VLMs) using zero- and few-shot settings and found they struggle with our risk assessment and navigational tasks. We validate our mmWalk-finetuned model on real-world datasets and show the effectiveness of our dataset for advancing multi-modal walking assistance.