Open-pit mine scheduling is a critical process for maximizing economic return under complex geotechnical and operational constraints. While Mixed-Integer Linear Programming (MILP) provides mathematically optimal baselines, its exponential computational complexity and inability to adapt in real time limit its practical deployment in dynamic industrial environments. This work introduces a simulator-driven Large Language Model (LLM) scheduling framework in which the LLM acts as an autonomous decision-making agent, guided at each step by a custom simulator that encodes geotechnical precedence, extraction-processing coupling, and dynamic capacity constraints directly into the action generation mechanism. Operating entirely zero-shot within a closed, data-secure environment, the framework produces complete, interpretable extraction and processing schedules without cloud-based inference, domain-specific fine-tuning, or retraining. To provide a trustworthy performance benchmark, a novel MILP formulation is developed that incorporates realistic operational and geotechnical constraints. Evaluated across mining instances of varying scale and time periods, the LLM-based framework recovers between 94\% and 99\% of the MILP optimal NPV while scaling linearly in computation time. These results position simulator-constrained LLM agents as a practical and scalable alternative to classical optimization for long-horizon industrial scheduling under complex operational constraints.