Zero-shot composed image retrieval (ZS-CIR) retrieves a target image from a reference image and a text modification without human-annotated CIR triplets. Projection-based ZS-CIR methods are attractive because they do not rely on LLMs at inference and remain lightweight, but they often underperform LLM-based approaches on complex semantic modifications. This gap reflects a semantic transition bottleneck in projection-based ZS-CIR: endpoint-level matching can let the edit text act as a target-side attribute cue rather than grounding it as a source-conditioned semantic transition. We further show that adding semantic transition supervision to the same text adapter creates an endpoint--transition conflict between endpoint alignment and semantic transition alignment. To address this conflict, DeCIR decouples endpoint and transition learning. It constructs paired forward/reverse edit tuples from image-caption pairs, trains separate low-rank text adapter branches for endpoint alignment and semantic transition alignment, and merges them with Low-Rank Directional Merge (LRDM) into one deployable adapter. Extensive experiments on CIRR, CIRCO, FashionIQ, and GeneCIS demonstrate that DeCIR consistently improves projection-based ZS-CIR without increasing inference complexity.