As Large Language Models (LLMs) scale up, inference efficiency becomes a critical bottleneck. Multi-Token Prediction (MTP) could accelerate LLM inference by predicting multiple future tokens in parallel. However, existing MTP approaches still face two challenges: limited acceptance rates of MTP heads, and difficulties in jointly training multiple MTP heads. Therefore, we propose MTP-D, a simple yet effective self-distillation method with minimal additional training cost, which boosts MTP head acceptance rates (+7.5\%) while maximumly preserving main-head performance. We also introduce a looped extension strategy for MTP-D, enabling effective and economical MTP head extension and further significant inference speedup to 1-head MTP (+220.4\%). Moreover, we systematically explore and validate key insights on the distillation strategies and the potential scalability of MTP through extensive experiments on seven benchmarks. These results demonstrate that our MTP-D and looped extension strategy effectively enhance MTP-head performance and inference efficiency, facilitating the practical usage of MTP in LLMs.