In this paper, we propose CitaLaw, the first benchmark designed to evaluate LLMs' ability to produce legally sound responses with appropriate citations. CitaLaw features a diverse set of legal questions for both laypersons and practitioners, paired with a comprehensive corpus of law articles and precedent cases as a reference pool. This framework enables LLM-based systems to retrieve supporting citations from the reference corpus and align these citations with the corresponding sentences in their responses. Moreover, we introduce syllogism-inspired evaluation methods to assess the legal alignment between retrieved references and LLM-generated responses, as well as their consistency with user questions. Extensive experiments on 2 open-domain and 7 legal-specific LLMs demonstrate that integrating legal references substantially enhances response quality. Furthermore, our proposed syllogism-based evaluation method exhibits strong agreement with human judgments.