Large Language Models (LLMs) often exhibit homogenized cultural perspectives. While the World Values Survey (WVS) provides a gold standard for mapping human values, traditional direct prompting of LLMs on WVS often fails to access the model's latent cultural depth, leading to safety-aligned refusals or neutral responses. Here, we propose a generalizable framework for cultural evaluation and intervention that transitions from abstract queries to scenario-based behavioral probing. By extracting implicit token probabilities across 300 situational dilemmas, we bypass surface-level alignment to map the latent coordinates of LLMs cultural value. We further introduce activation steering to shift these internal alignments during the forward pass without retraining. Across multiple LLMs, we find substantial variation in adaptability and uncover a consistent phenomenon of latent entanglement, where interventions along one cultural dimension induce shifts along another. These results suggest that cultural values are encoded as coupled structures, limiting precise alignment. This work establishes a computationally efficient framework for cultural steering, highlighting the structural complexities when navigating global value with LLMs.