Retrieval-augmented generation (RAG) improves knowledge-intensive question answering by incorporating external evidence. However, existing RAG methods still suffer from hallucinations and subtle reasoning errors. Recent studies introduce external critics to refine RAG outputs, yet they often provide coarse-grained and weakly structured feedback, exhibit over-aggressive intervention, and lead to noisy and unreliable refinement, limiting their effectiveness for correction. To tackle these issues, we propose CRITIC-R1, a structured critic framework that formulates and learns RAG critique as an explicit error diagnosis problem using reinforcement learning (RL). Our framework categorizes common RAG errors into multiple diagnostic dimensions, including verdict, error location, reasoning analysis, and fix generation. To learn these capabilities, we design two reward functions: Conservative Judgement Alignment (CJA) first encourages calibrated high-level judgements while mitigating the over-aggressive phenomenon, whereas Diagnostic Quality Alignment (DQA) further improves fine-grained diagnostic feedback through gated rewards. We train the critic model using GRPO-based RL with process-level supervision collected from external LLM teacher models. Experiments across five QA benchmarks show that CRITIC-R1 consistently improves answer quality over strong RAG baselines. Our source code is available at https://anonymous.4open.science/r/critic-r1-FCB0