While LLM agents have demonstrated remarkable task-oriented abilities such as planning, reasoning, and action, few works have treated them as complete human personalities where emotional dimensions hold equal importance. In this paper, we introduce a novel benchmark to systematically assess whether LLM agents can simulate coherent, human-like psychology. Specifically, our benchmark constructs 11 diverse human characters grounded in orthogonal Big Five personality traits, with each profile deeply integrated with 1,000 structured autobiographical-style episodic memories distributed across theory-grounded developmental life stages. To rigorously evaluate the psychological manifestations of LLMs, we designed a curated suite of 64 decision-making scenarios, guided by the DIAMONDS taxonomy, a psychological framework that characterizes situations along eight dimensions: Duty, Intellect, Adversity, Mating, pOsitivity, Negativity, Deception, and Sociality. By subjecting agents to varying scenarios, the benchmark evaluates whether they can consolidate their innate personality traits and autobiographical memories to make behavioral decisions that are consistent with their specific psychological profiles. After systematic human validation and filtering, we obtained a benchmark consisting of 673 multiple-choice questions (MCQs). We believe this benchmark provides a principled and scalable testbed for studying human-like emotions, personality consistency, and value-consistent behavioural decision-making in LLM-based agents.