Large Language Models (LLMs) have displayed astonishing abilities in various tasks, especially in text generation, classification, question answering, etc. However, the reasoning ability of LLMs still faces many debates. The inherent ambiguity of Natural Language (NL) limits LLMs' ability to perform verifiable reasoning, making its answers lack coherence and trustworthy support. To tackle the above problems, we propose a novel framework named FANS: Formal ANswer Selection for Natural Language Math Reasoning Using Lean4. To the best of our knowledge, it is the first framework that utilizes Lean4 to enhance LLMs' NL math reasoning ability. In particular, given an NL math question and LLM-generated answers, FANS first translates it into Lean4 theorem statements. Then it tries to prove it using a Lean4 prover and verify it by Lean4. Finally, it uses the FL result to assist in answer selection. It enhances LLMs' NL math ability in providing a computer-verifiable solution for its correct answer and proposes an alternative method for answer selection beyond the reward model. Extensive experiments indicate the effectiveness of our framework. It can improve the accuracy rate of reward model enhanced LLMs in the MATH-500 dataset by at most 1.91% and AMC-23 by at most 8.33% on strong reward-model baselines. In some particular fields like number theory that Lean4 experts in, we can even select all correct solutions. The qualitative analysis also shows our framework can make NL results formally backed by Lean4 proofs. As a pioneering work in the corresponding field, we will open-source all our models and datasets to further boost the development of the field.