This paper presents a comprehensive evaluation framework for aligning Persian Large Language Models (LLMs) with critical ethical dimensions, including safety, fairness, and social norms. It addresses the gaps in existing LLM evaluation frameworks by adapting them to Persian linguistic and cultural contexts. This benchmark creates three types of Persian-language benchmarks: (i) translated data, (ii) new data generated synthetically, and (iii) new naturally collected data. We translate Anthropic Red Teaming data, AdvBench, HarmBench, and DecodingTrust into Persian. Furthermore, we create ProhibiBench-fa, SafeBench-fa, FairBench-fa, and SocialBench-fa as new datasets to address harmful and prohibited content in indigenous culture. Moreover, we collect extensive dataset as GuardBench-fa to consider Persian cultural norms. By combining these datasets, our work establishes a unified framework for evaluating Persian LLMs, offering a new approach to culturally grounded alignment evaluation. A systematic evaluation of Persian LLMs is performed across the three alignment aspects: safety (avoiding harmful content), fairness (mitigating biases), and social norms (adhering to culturally accepted behaviors). We present a publicly available leaderboard that benchmarks Persian LLMs with respect to safety, fairness, and social norms at: https://huggingface.co/spaces/MCILAB/LLM_Alignment_Evaluation.