We propose a scalable method for constructing a temporal opinion knowledge base with large language models (LLMs) as automated annotators. Despite the demonstrated utility of time-series opinion analysis of text for downstream applications such as forecasting and trend analysis, existing methodologies underexploit this potential due to the absence of temporally grounded fine-grained annotations. Our approach addresses this gap by integrating well-established opinion mining formulations into a declarative LLM annotation pipeline, enabling structured opinion extraction without manual prompt engineering. We define three data models grounded in sentiment and opinion mining literature, serving as schemas for structured representation. We perform rigorous quantitative evaluation of our pipeline using human-annotated test samples. We carry out the final annotations using two separate LLMs, and inter-annotator agreement is computed label-wise across the fine-grained opinion dimensions, analogous to human annotation protocols. The resulting knowledge base encapsulates time-aligned, structured opinions and is compatible with applications in Retrieval-Augmented Generation (RAG), temporal question answering, and timeline summarisation.