Retrieval-Augmented Generation (RAG) aims to reduce hallucination by grounding answers in retrieved evidence, yet hallucinated answers remain common even when relevant documents are available. Existing evaluations focus on answer-level or passage-level accuracy, offering limited insight into how evidence is used during generation. In this work, we introduce a facet-level diagnostics framework for QA that decomposes each input question into atomic reasoning facets. For each facet, we assess evidence sufficiency and grounding using a structured Facet x Chunk matrix that combines retrieval relevance with natural language inference-based faithfulness scores. To diagnose evidence usage, we analyze three controlled inference modes: Strict RAG, which enforces exclusive reliance on retrieved evidence; Soft RAG, which allows integration of retrieved evidence and parametric knowledge; and LLM-only generation without retrieval. Comparing these modes enables thorough analysis of retrieval-generation misalignment, defined as cases where relevant evidence is retrieved but not correctly integrated during generation. Across medical QA and HotpotQA, we evaluate three open-source and closed-source LLMs (GPT, Gemini, and LLaMA), providing interpretable diagnostics that reveal recurring facet-level failure modes, including evidence absence, evidence misalignment, and prior-driven overrides. Our results demonstrate that hallucinations in RAG systems are driven less by retrieval accuracy and more by how retrieved evidence is integrated during generation, with facet-level analysis exposing systematic evidence override and misalignment patterns that remain hidden under answer-level evaluation.