Current language model training paradigms typically terminate learning upon reaching the end-of-sequence (<eos>) token, overlooking the potential learning opportunities in the post-completion space. We propose Post-Completion Learning (PCL), a novel training framework that systematically utilizes the sequence space after model output completion, to enhance both the reasoning and self-evaluation abilities. PCL enables models to continue generating self-assessments and reward predictions during training, while maintaining efficient inference by stopping at the completion point. To fully utilize this post-completion space, we design a white-box reinforcement learning method: let the model evaluate the output content according to the reward rules, then calculate and align the score with the reward functions for supervision. We implement dual-track SFT to optimize both reasoning and evaluation capabilities, and mixed it with RL training to achieve multi-objective hybrid optimization. Experimental results on different datasets and models demonstrate consistent improvements over traditional SFT and RL methods. Our method provides a new technical path for language model training that enhances output quality while preserving deployment efficiency.