While Large Language Models (LLMs) have significantly advanced natural language processing, aligning them with human preferences remains an open challenge. Although current alignment methods rely primarily on explicit feedback, eye-tracking (ET) data offers insights into real-time cognitive processing during reading. In this paper, we present OASST-ETC, a novel eye-tracking corpus capturing reading patterns from 24 participants, while evaluating LLM-generated responses from the OASST1 dataset. Our analysis reveals distinct reading patterns between preferred and non-preferred responses, which we compare with synthetic eye-tracking data. Furthermore, we examine the correlation between human reading measures and attention patterns from various transformer-based models, discovering stronger correlations in preferred responses. This work introduces a unique resource for studying human cognitive processing in LLM evaluation and suggests promising directions for incorporating eye-tracking data into alignment methods. The dataset and analysis code are publicly available.